Thermal Poling of Silica

Alexander Strauss, Sven Brueckner, Ulrich Roepke, Hartmut Bartelt
  1. Leibniz-Institut für Photonische Technologien e.V.

alexander [dot] strauss [at] ipht-jena [dot] de

Glass, an amorphous centrosymmetric material, naturally exhibits no second-order optical susceptibility (chi2). Therefore typical second-order effects such as electrooptic effect or second harmonic generation do not exist. During thermal poling we applied a high voltage (kV-range) on a silica sample, which was heated up before to 270-330°C. After cooling and switching off the voltage, a frozen-in electric field exists in the material (EDC~107 V/m). This electric field breaks the inversion symmetry, and in combination with the intrinsic third-order nonlinearity an effective susceptibility chi2eff ~ chi3*EDC arises. This poled samples were characterised by second harmonic measurements. We will report on the influence of different poling-parameters (voltage, length of time, temperature) on second harmonic generation, as well as on the stability of the generated second-order nonlinearity concerning UV-radiation, temperature and aging.

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@inproceedings{strauss2005p53,
  author     = {Strauss, Alexander and Brueckner, Sven and Roepke, Ulrich and Bartelt, Hartmut},
  title      = {{Thermal Poling of Silica}},
  booktitle  = {DGaO-Proceedings 2005},
  series     = {DGaO-Proceedings},
  eventtitle = {106. Jahrestagung der DGaO},
  eventdate  = {2005-05-17/2005-05-20},
  venue      = {Wrocław},
  publisher  = {Deutsche Gesellschaft für angewandte Optik e.V.},
  year       = {2005},
  pages      = {P53},
  url        = {https://dgao-proceedings.de/paper/106-p53}
}
106. Jahrestagung der DGaO · Wrocław · 2005